My question is how do I fix the weird smudging issue? Is it a stringing issue? Or something else specifically related to multi-material/ams settings? 3mf for this print
As @Olias mentioned, it’s probably contaminated. Could be by the nozzle not wiping off cleanly during the filament switch over, or the flush/purge is not clean enough.
One thing that you could try is to tweak the Flushing Volumes when it’s switching between the white & black colors: