I would be interested in seeing the claims from those manufacturers.
This is a summary that ChatGPT wrote. I will add some citations at the bottom:
Moisture in thermoplastic filament is continuously exchanged with the surrounding air. Water molecules can move into and out of the plastic at ordinary storage temperatures; they are not generally locked inside until the filament reaches a particular “release temperature.”
Assuming the filament has been stored long enough to reach equilibrium with its environment, its moisture content is determined by the filament’s material, the storage temperature, and the surrounding relative humidity. The filament will not necessarily contain the same percentage of water as another plastic stored at the same RH. PETG, PLA, nylon, and different grades or brands of PETG can all have different moisture-equilibrium levels.
Relative humidity is therefore a useful indication of the conditions driving moisture absorption or loss, but it is not a direct measurement of the water inside the filament. RH also changes with temperature, so both temperature and RH matter. In real storage situations, the filament may take hours or days to reach equilibrium, especially after being moved from a humid environment into a dry box.
Heating mainly speeds up the movement and evaporation of water. It does not usually cross a sharp threshold where previously unavailable water suddenly becomes free. Heating makes the polymer chains and water molecules more mobile, allowing moisture to diffuse out faster. The recommended drying temperature is chosen to remove moisture efficiently without deforming or damaging the filament.
For PETG, drying matters because absorbed water can react with the polymer when it is melted. This hydrolysis can reduce the polymer’s molecular weight and lead to popping, bubbles, stringing, poor surfaces, reduced strength, and inconsistent extrusion.
Thus, if filament is truly equilibrated with its storage environment, a lower-RH environment generally means drier filament—but the RH reading alone cannot tell you its exact moisture content. For practical printing, follow the manufacturer’s drying recommendation when the filament has been exposed to humid air or shows signs of moisture.
Citations:
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Water activity and equilibrium
IUPAC Gold Book, “water activity”
Defines water activity in terms of the chemical potential of water. For air in ordinary storage conditions, water activity is approximately related to RH by:
aw≈100RH
This supports the idea that a polymer exposed to air tends toward a moisture content determined by the material, temperature, and water activity—not by RH alone.
IUPAC Gold Book:
https://goldbook.iupac.org/terms/view/W06642
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Polymer diffusion and sorption
Crank, J., The Mathematics of Diffusion, 2nd ed., Oxford University Press, 1975.
This is a standard reference on diffusion. It explains why moisture can move through a polymer at ordinary temperatures, while also showing why the process may be slow and why heating accelerates it.
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Polymer solubility and diffusion
Brandrup, J., Immergut, E. H., and Grulke, E. A., eds., Polymer Handbook, 4th ed., Wiley, 1999.
The chapters on diffusion, permeability, and polymer–solvent interactions cover the concepts behind moisture sorption, equilibrium concentration, temperature dependence, and diffusion through polymers.
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Diffusion in glassy polymers
Vrentas, J. S. and Duda, J. L., “Diffusion in Polymer–Solvent Systems. I. Reexamination of the Free-Volume Theory,” Journal of Polymer Science: Polymer Physics Edition, 15, 403–416, 1977.
This work describes why diffusion depends strongly on temperature and polymer-chain mobility. It is relevant to the observation that drying becomes much faster when a polymer is heated, without implying a sharp temperature at which water suddenly becomes free.